PENGARUH PENAMBAHAN KARBON AKTIF DARI TANAH GAMBUT TERHADAP KAPASITANSI ELEKTRODA SUPERKAPASITOR BERBAHAN DASAR KARBON AKTIF CANGKANG KELAPA SAWIT
DOI:
https://doi.org/10.31629/zarah.v6i2.562Keywords:
karbon aktif, cangkang kelapa sawit, tanah gambut, superkapasitor, kapasitansiAbstract
Pengaruh penambahan karbon aktif tanah gambut terhadap kinerja superkapasitor berbahan dasar cangkang kelapa sawit telah dipelajari. Karbon aktif dari tanah gambut dibuat dengan menambahkan KOH 10 M dan dilakukan perendaman pada perbandingan massa 1: 4 antara karbon dengan KOH. Karbon aktif yang dihasilkan dikarakterisasi dengan XRD (X-Ray Difraksi), SEM-EDX (Scanning Elektron Microscopy-Energi Dispersive X - Ray), dan FTIR (Fourier Transform infrared Spektroscopy). Penambahan karbon aktif dari tanah gambut memberikan nilai kapasitansi meningkat menjadi 8063 kali lebih besar pada perbandingan masaa 1: 2 dengan luas luas pelat elektroda 3x3 cm2, konsentrasi elektrolit H3PO4 0,3 N dan waktu pengisian 15 menit. Pencampuran Karbon aktif dari tanah gambut dan cangkang kelapa sawit memiliki kinerja yang baik sebagai bahan elektroda superkapasitor.
References
Boyea, J.M; R.E. Camacho; S. P. Turano; W. J. Ready. (2007). Carbon Nanotube-Based Supercapacitors: Technologies and Markets. Nanotechnology Law &Business, 585 -593.
Chao, P., Xing-bin, Y., Ru-tao, W., Jun-wei, L., Yu-jing, O., Qun-ji, X., (2013). Promising Actived Carbons Derived From Waste Tea-Leaves And Their Application In High Performance Supercapacitors Electrodes. Electrochimica Acta, 401-408.
Chaitra, K. Vinny, R. T. Sivaraman, P. Narendra Reddy. Chunyan, Hu. Krishna, Venkatesh. Vivek, C. S. Nagaraju, N. Kathyayini, N. (2016). Journal of Energy Chemistry, 6(28), 1-7.
Chen-Hao, Wang, Wei-Chen, Hsin-cheng, Hsu. Bing-Yuan, Yao. (2016). High Capacitance KOH Activated Nitrogen-Containing Porous Carbon Material From Waste Coffee Grounds In Supercapacitor. Advanced Powder Technology, 1387-1395.
Ferreira, C.S, Passos, R.R. Pocrifka, L.A. (2014). Synthesis and Properties of Ternary Mixture of Nikel/Cobalt/Tin Oxides for Supercapacitor. Power Sources, 271, 104-107.
Guo, Yanping, David A. Rockstraw. (2007). Activated Carbons Prepared From Rice Hull By One-Step Phosphoric Acid Activation. Microporous and Mesoporous Materials,12–19.
Hartono, Singgih, Ratnawati. (2010). Pembuatan Karbon Aktif dari Tempurung Kelapa Sawit dengan Metode Aktivasi Kimia. Jurnal Sains Materi Indonesia, 12 (1), 12-16.
Hermansyah, Aziz, Olly, N. T. Admin, A. Wahyu, R. (2016). Electrical Properties Of Supercapasitor Electrode Based On Activated Carbon From Waste Palm Kernel Shells. Der Pharma Chemica, 8, (15), 227-232.
Olly, N.T. Admin, A. Gesti, U. (2015). Pemanfaatan Limbah Tempurung Biji Karet Sebagai Bahan Elektroda Superkapasitor. Laporan Penelitian Dosen Muda, Universitas Andalas.
Olly, N.T, Hermansyah, A, Emriadi. (2016). Performance of TiO2-Carbon on Ceramic Template with Sodium Hydroxide Activation as Supercapasitors Electrode Materials. Der Pharma Chemica, 8 (17), 26-30.
Memori, R. Fery, I. Mikrajuddin, A. Khairurrijal. (2013) Synthesys and Characterization of Supercapacitor Using Nano-sized ZnO/Nanoporous Carbon Electrodes and PVA-based Polymer-Hydrogel Electrolytes. Materials Science Forum, 737, 191-196.
Memori, R. Fery, I. Mikrajuddin, A. Khairurrijal. (2014). Hydrogel-Polymer Electrolytes Based on Polyvinyl Alcohol and Hydroxyethylcellulose for Supercapacitor Applications. Electrochemical Science, 9, 4251-4256.
Soon, H.K. Eunji, L. Bum, S.K. Sang, G.K. Byung, J.L, Myung, S.K. Ji, C.J. (2014). Activated Carbon Aerogel as Electrode Material for Coin-Type EDLC Cell in Organic Electrolyte. Current Applied Physics, 14, 603-607.
Tumirah, Khadiran, Mohd, Zobir Huseein. Zulkarnain, Zainal. Rafeadah, Rusli. (2015). Textural and Chemical Properties of Activated Carbon Prepared from Tropical Peat Soil by Chemical Activation method. BioResources, 10 (1), 986- 1007.
Yacob, A. R. Majid, Z. A, Dewi, R. S. Inderan. (2008). Comparison of Various Source of High Surface Area Carbon Prepared by Different Type of Activation. The Malaysian Journal of Analytical Sciences. 12 (1), 264-271.
Zhang, Wenli, Nan, Lin. Debo, Liu, Jinhui, Xu. Jinxin, Sha. Jian, Yin, Xiaobo, Tan. Huiping, Y. Haiyan, L. Haibo, Lin. (2007). Direct Carbonization Of Rice Husk To Prepare Porous Carbon For Supercapacitor Applications. Energy, 128, 618-625.
Chao, P., Xing-bin, Y., Ru-tao, W., Jun-wei, L., Yu-jing, O., Qun-ji, X., (2013). Promising Actived Carbons Derived From Waste Tea-Leaves And Their Application In High Performance Supercapacitors Electrodes. Electrochimica Acta, 401-408.
Chaitra, K. Vinny, R. T. Sivaraman, P. Narendra Reddy. Chunyan, Hu. Krishna, Venkatesh. Vivek, C. S. Nagaraju, N. Kathyayini, N. (2016). Journal of Energy Chemistry, 6(28), 1-7.
Chen-Hao, Wang, Wei-Chen, Hsin-cheng, Hsu. Bing-Yuan, Yao. (2016). High Capacitance KOH Activated Nitrogen-Containing Porous Carbon Material From Waste Coffee Grounds In Supercapacitor. Advanced Powder Technology, 1387-1395.
Ferreira, C.S, Passos, R.R. Pocrifka, L.A. (2014). Synthesis and Properties of Ternary Mixture of Nikel/Cobalt/Tin Oxides for Supercapacitor. Power Sources, 271, 104-107.
Guo, Yanping, David A. Rockstraw. (2007). Activated Carbons Prepared From Rice Hull By One-Step Phosphoric Acid Activation. Microporous and Mesoporous Materials,12–19.
Hartono, Singgih, Ratnawati. (2010). Pembuatan Karbon Aktif dari Tempurung Kelapa Sawit dengan Metode Aktivasi Kimia. Jurnal Sains Materi Indonesia, 12 (1), 12-16.
Hermansyah, Aziz, Olly, N. T. Admin, A. Wahyu, R. (2016). Electrical Properties Of Supercapasitor Electrode Based On Activated Carbon From Waste Palm Kernel Shells. Der Pharma Chemica, 8, (15), 227-232.
Olly, N.T. Admin, A. Gesti, U. (2015). Pemanfaatan Limbah Tempurung Biji Karet Sebagai Bahan Elektroda Superkapasitor. Laporan Penelitian Dosen Muda, Universitas Andalas.
Olly, N.T, Hermansyah, A, Emriadi. (2016). Performance of TiO2-Carbon on Ceramic Template with Sodium Hydroxide Activation as Supercapasitors Electrode Materials. Der Pharma Chemica, 8 (17), 26-30.
Memori, R. Fery, I. Mikrajuddin, A. Khairurrijal. (2013) Synthesys and Characterization of Supercapacitor Using Nano-sized ZnO/Nanoporous Carbon Electrodes and PVA-based Polymer-Hydrogel Electrolytes. Materials Science Forum, 737, 191-196.
Memori, R. Fery, I. Mikrajuddin, A. Khairurrijal. (2014). Hydrogel-Polymer Electrolytes Based on Polyvinyl Alcohol and Hydroxyethylcellulose for Supercapacitor Applications. Electrochemical Science, 9, 4251-4256.
Soon, H.K. Eunji, L. Bum, S.K. Sang, G.K. Byung, J.L, Myung, S.K. Ji, C.J. (2014). Activated Carbon Aerogel as Electrode Material for Coin-Type EDLC Cell in Organic Electrolyte. Current Applied Physics, 14, 603-607.
Tumirah, Khadiran, Mohd, Zobir Huseein. Zulkarnain, Zainal. Rafeadah, Rusli. (2015). Textural and Chemical Properties of Activated Carbon Prepared from Tropical Peat Soil by Chemical Activation method. BioResources, 10 (1), 986- 1007.
Yacob, A. R. Majid, Z. A, Dewi, R. S. Inderan. (2008). Comparison of Various Source of High Surface Area Carbon Prepared by Different Type of Activation. The Malaysian Journal of Analytical Sciences. 12 (1), 264-271.
Zhang, Wenli, Nan, Lin. Debo, Liu, Jinhui, Xu. Jinxin, Sha. Jian, Yin, Xiaobo, Tan. Huiping, Y. Haiyan, L. Haibo, Lin. (2007). Direct Carbonization Of Rice Husk To Prepare Porous Carbon For Supercapacitor Applications. Energy, 128, 618-625.
1.png)
