UTILIZATION OF CHITOSAN IN BIOSORPTION TECHNOLOGY: A REVIEW OF ADSORPTION CAPACITY AND ITS APPLICATIONS FOR HEAVY METALS

Authors

  • Hilfi pardi Department of Chemistry, Faculty of Marine Engineering and Technology, Raja Ali Haji Maritime University Senggarang, Tanjungpinang 29100, Indonesia
  • Meicyntia Bella Department of Chemistry, Faculty of Marine Engineering and Technology, Raja Ali Haji Maritime University Senggarang, Tanjungpinang 29100, Indonesia
  • Muhammad Rizki Ramadhani Department of Chemistry, Faculty of Marine Engineering and Technology, Raja Ali Haji Maritime University Senggarang, Tanjungpinang 29100, Indonesia
  • Putri Ramadani Department of Chemistry, Faculty of Marine Engineering and Technology, Raja Ali Haji Maritime University Senggarang, Tanjungpinang 29100, Indonesia

Keywords:

adsorption capacity, biosorption mechanisms, environmental remediation, heavy metal, wastewater treatment

Abstract

The rising levels of heavy metal pollution in water bodies present major environmental and public health issues. Conventional methods for remediation often come with high costs and produce secondary waste, which can pose additional environmental risks. As an alternative, chitosan—a natural, biopolymer derived from chitin—has gained attention as a promising biosorbent for heavy metal removal. Its advantages include biocompatibility, biodegradability, and a strong ability to bind metal ions effectively. This review explores chitosan’s capacity to adsorb various heavy metals and examines its practical applications in biosorption technology. Key factors that impact its adsorption efficiency, such as solution pH, metal concentration, and contact time, are discussed. Additionally, structural modifications to enhance chitosan’s performance, including cross-linking and nanoparticle incorporation, are analyzed to highlight improvements in adsorption efficiency. By assessing these elements, this review aims to offer a comprehensive perspective on the role of chitosan in environmental management, particularly for treating heavy metal contamination in wastewater. The findings underscore chitosan's potential as a sustainable solution in pollution control, emphasizing its advantages over traditional methods and its capacity to contribute to cleaner water resources.

References

Akhtar, N., Ishak, M. I. S., Bhawani, S. A., & Umar, K. (2021). Various natural and anthropogenic factors responsible for water quality degradation: A review. Water, 13(19), 2660.

Ayach, J., El Malti, W., Duma, L., Lalevée, J., Al Ajami, M., Hamad, H., & Hijazi, A. (2024). Comparing conventional and advanced approaches for heavy metal removal in wastewater treatment: An in-depth review emphasizing filter-based strategies. Polymers, 16(14), 1959.

Basem, A., Jasim, D. J., Majdi, H. S., Mohammed, R. M., Ahmed, M., & Al-Rubaye, A. H. (2024). Adsorption of heavy metals from wastewater by chitosan: A review. Results in Engineering, 102404.

Briffa, J., Sinagra, E., & Blundell, R. (2020). Heavy metal pollution in the environment and their toxicological effects on humans. Heliyon, 6(9).

Dobre, T., Isopencu, G. O., Ahmed, S. B., & Deleanu, I. M. (2024). Heavy metal pollution and solutions for its control: General aspects with a focus on cobalt removal and recovery from aqueous systems. ChemEngineering, 8(6), 118.

Eivazzadeh-Keihan, R., Radinekiyan, F., Asgharnasl, S., Maleki, A., & Bahreinizad, H. (2020). A natural and eco-friendly magnetic nanobiocomposite based on activated chitosan for heavy metals adsorption and the in-vitro hyperthermia of cancer therapy. Journal of Materials Research and Technology, 9(6), 12244–12259.

Fatullayeva, S., Tagiyev, D., Zeynalov, N., Mammadova, S., & Aliyeva, E. (2022). Recent advances of chitosan-based polymers in biomedical applications and environmental protection. Journal of Polymer Research, 29(7), 259.

Ibrahim, M. A., Alhalafi, M. H., Emam, E. A. M., Ibrahim, H., & Mosaad, R. M. (2023). A review of chitosan and chitosan nanofiber: Preparation, characterization, and its potential applications. Polymers, 15(13), 2820.

Ji, Z., Zhang, Y., Wang, H., & Li, C. (2022). Research progress in the removal of heavy metals by modified chitosan. Tenside Surfactants Detergents, 59(4), 281–293.

Kaczorowska, M. A., & Bożejewicz, D. (2024). The application of chitosan-based adsorbents for the removal of hazardous pollutants from aqueous solutions—A review. Sustainability, 16(7), 2615.

Ojha, A., Jaiswal, S., Thakur, P., & Mishra, S. K. (2023). Bioremediation techniques for heavy metal and metalloid removal from polluted lands: A review. International Journal of Environmental Science and Technology, 20(9), 10591–10612.

Omer, A. M., Dey, R., Eltaweil, A. S., Abd El-Monaem, E. M., & Ziora, Z. M. (2022). Insights into recent advances of chitosan-based adsorbents for sustainable removal of heavy metals and anions. Arabian Journal of Chemistry, 15(2), 103543.

Priya, A. K., Gnanasekaran, L., Dutta, K., Rajendran, S., Balakrishnan, D., & Soto-Moscoso, M. (2022). Biosorption of heavy metals by microorganisms: Evaluation of different underlying mechanisms. Chemosphere, 307, 135957.

Radha, E., Gomathi, T., Sudha, P. N., Latha, S., Ghfar, A. A., & Hossain, N. (2021). Adsorption studies on removal of Pb (II) and Cd (II) ions using chitosan derived copolymeric blend. Biomass Conversion and Biorefinery, 1-16.

Raji, Z., Karim, A., Karam, A., & Khalloufi, S. (2023). Adsorption of heavy metals: Mechanisms, kinetics, and applications of various adsorbents in wastewater remediation—A review. Waste, 1(3), 775–805.

Rahman, A. (2024). Promising and environmentally friendly removal of copper, zinc, cadmium, and lead from wastewater using modified shrimp-based chitosan. Water, 16(1), 184.

Rahman, A., Haque, M. A., Ghosh, S., Shinu, P., Attimarad, M., & Kobayashi, G. (2023). Modified shrimp-based chitosan as an emerging adsorbent removing heavy metals (chromium, nickel, arsenic, and cobalt) from polluted water. Sustainability, 15(3), 2431.

Saraswathi, M., & Madhuri, R. J. (2020). Chitosan as a heavy metal adsorbent in waste water treatment. In Advances in Computational and Bio-Engineering: Proceeding of the International Conference on Computational and Bio Engineering (pp. 649–654). Springer International Publishing.

Shankar, S., Joshi, S., & Srivastava, R. K. (2023). A review on heavy metal biosorption utilizing modified chitosan. Environmental Monitoring and Assessment, 195(11), 1350.

Sonker, S., Fulke, A. B., & Monga, A. (2024). Recent trends on bioremediation of heavy metals; An insight with reference to the potential of marine microbes. International Journal of Environmental Science and Technology, 1-12.

Soubhagya, A. S., Moorthi, A., & Prabaharan, M. (2020). Preparation and characterization of chitosan/pectin/ZnO porous films for wound healing. International Journal of Biological Macromolecules, 157, 135–145.

Staszak, K., & Regel-Rosocka, M. (2024). Removing heavy metals: Cutting-edge strategies and advancements in biosorption technology. Materials, 17(5), 1155.

Wang, J., & Chen, C. (2014). Chitosan-based biosorbents: Modification and application for biosorption of heavy metals and radionuclides. Bioresource Technology, 160, 129–141.

Wang, K., Zhang, F., Xu, K., Che, Y., Qi, M., & Song, C. (2023). Modified magnetic chitosan materials for heavy metal adsorption: A review. RSC Advances, 13(10), 6713–6736.

Yang, W., Liao, Q., & Gusiatin, M. Z. (2024). Remediation and health risks of heavy metal contaminated soils. Frontiers in Environmental Science, 12, 1501443.

Zhang, W., Miao, A. J., Wang, N. X., Li, C., Sha, J., Jia, J., ... & Ok, Y. S. (2022). Arsenic bioaccumulation and biotransformation in aquatic organisms. Environment International, 163, 107221.

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Published

2025-06-27